Phenylmagnesium Bromide

SECTION 1. IDENTIFICATION

Product Name: Phenylmagnesium Bromide

Product Number: All applicable American Elements product codes, e.g. PHL-MGBR-01-SOL

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CAS #: 100-58-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351

Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)GHS02 FlameFlam. Liq. 2H225 Highly flammable liquid and vapor.GHS05 CorrosionSkin Corr. 1B H314 Causes severe skin burns and eye damage.Hazards not otherwise classifiedNo information known.Label elementsGHS label elementsThe product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)Hazard pictograms

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GHS02 GHS05Signal wordDangerHazard-determining components of labeling:Phenylmagnesium bromideHazard statementsH225 Highly flammable liquid and vapor.H314 Causes severe skin burns and eye damage.Precautionary statementsP210Keep away from heat/sparks/open flames/hot surfaces. No smoking.P260Do not breathe dust/fume/gas/mist/vapours/spray.P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P405Store locked up.P501Dispose of contents/container in accordance with local/regional/national/international regulations.WHMIS classificationD2B – Toxic material causing other toxic effectsE – Corrosive materialClassification systemHMIS ratings (scale 0-4)(Hazardous Materials Identification System)Health (acute effects) = 3Flammability = 3Physical Hazard = 2Other hazardsResults of PBT and vPvB assessmentPBT:Not applicable.vPvB:Not applicable.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: MixturesDangerous components:100-58-3 Phenylmagnesium bromide Skin Corr. 1B, H314; Eye Dam. 1, H31896-47-9 2-Methyltetrahydrofuran Flam. Liq. 2, H225

SECTION 4. FIRST AID MEASURES

Description of first aid measuresGeneral informationImmediately remove any clothing soiled by the product.After inhalationSupply fresh air. If required, provide artificial respiration. Keep patient warm.Seek immediate medical advice.After skin contactImmediately wash with water and soap and rinse thoroughly.Seek immediate medical advice.After eye contactRinse opened eye for several minutes under running water. Then consult a doctor.After swallowingSeek medical treatment.Information for doctorMost important symptoms and effects, both acute and delayedCauses severe skin burns.Causes serious eye damage.Indication of any immediate medical attention and special treatment neededNo further relevant information available.

SECTION 5. FIREFIGHTING MEASURES

Extinguishing mediaSuitable extinguishing agentsIn case of fire, use sand, carbon dioxide or powdered extinguishing agent. Never use water.For safety reasons unsuitable extinguishing agentsWaterSpecial hazards arising from the substance or mixtureReacts violently with waterIf this product is involved in a fire, the following can be released:Carbon monoxide and carbon dioxideHydrogen bromide (HBr)Metal oxide fumeAdvice for firefightersProtective equipment:Wear self-contained respirator.Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency proceduresWear protective equipment. Keep unprotected persons away.Ensure adequate ventilationKeep away from ignition sourcesEnvironmental precautions:Do not allow material to be released to the environment without proper governmental permits.Methods and material for containment and cleaning up:Keep away from ignition sources.Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Use neutralizing agent.Dispose of contaminated material as waste according to section 13.Ensure adequate ventilation.Do not flush with water or aqueous cleansing agentsPrevention of secondary hazards:Keep away from ignition sources.Reference to other sectionsSee Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

HandlingPrecautions for safe handlingHandle under dry protective gas.Keep container tightly sealed.Store in cool, dry place in tightly closed containers.Ensure good ventilation at the workplace.Open and handle container with care.Information about protection against explosions and fires:Protect against electrostatic charges.Fumes can combine with air to form an explosive mixture.Do not distill to dryness.Explosive peroxides may form, handle container cautiously.Conditions for safe storage, including any incompatibilitiesStorageRequirements to be met by storerooms and receptacles:Store in a cool location.Information about storage in one common storage facility:Store away from air.Store away from water/moisture.Store away from strong bases.Store away from oxidizing agents.Further information about storage conditions:Store under dry inert gas.This product is moisture sensitive.This product is air sensitive.Protect from humidity and water.Store in cool, dry conditions in well sealed containers.Avoid contact with air/oxygen (formation of peroxide).Check container pressure periodically to prevent explosive peroxides.Specific end use(s)No further relevant information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.Control parametersComponents with limit values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.Additional information:No dataExposure controlsPersonal protective equipmentGeneral protective and hygienic measuresThe usual precautionary measures for handling chemicals should be followed.Keep away from foodstuffs, beverages and feed.Remove all soiled and contaminated clothing immediately.Wash hands before breaks and at the end of work.Avoid contact with the eyes and skin.Maintain an ergonomically appropriate working environment.Breathing equipment:Use suitable respirator when high concentrations are present.Protection of hands:Impervious glovesCheck protective gloves prior to each use for their proper condition.The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.Penetration time of glove material (in minutes)Not determinedEye protection:Tightly sealed gogglesFull face protectionBody protection:Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

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Information on basic physical and chemical propertiesGeneral InformationAppearance:Form: LiquidColor: Not determinedOdor: Not determinedOdor threshold: Not determined.pH-value: Not determined.Change in conditionMelting point/Melting range: Not determinedBoiling point/Boiling range: Not determinedSublimation temperature / start: Not determinedFlammability (solid, gaseous)Not determined.Ignition temperature: Not determinedDecomposition temperature: Not determinedAuto igniting: Product is not selfigniting.Danger of explosion: May form explosive peroxides.Do not distill to dryness.Explosion limits:Lower: Not determinedUpper: Not determinedVapor pressure: Not determinedDensity: Not determinedRelative densityNot determined.Vapor densityNot determined.Evaporation rateNot determined.Solubility in / Miscibility with Water: Reacts violentlyPartition coefficient (n-octanol/water): Not determined.Viscosity:dynamic: Not determined.kinematic: Not determined.Other informationNo further relevant information available.

SECTION 10. STABILITY AND REACTIVITY

ReactivityReacts violently with water.May form explosive peroxides.Chemical stabilityStable under recommended storage conditions.Thermal decomposition / conditions to be avoided:Decomposition will not occur if used and stored according to specifications.Possibility of hazardous reactionsReacts with strong oxidizing agentsReacts violently with waterMay form explosive peroxides.Conditions to avoidNo further relevant information available.Incompatible materials:AirBasesOxidizing agentsWater/moistureHazardous decomposition products:Carbon monoxide and carbon dioxideHydrogen bromideMetal oxide fume

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effectsAcute toxicity:Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation of esophagus and stomach.LD/LC50 values that are relevant for classification:96-47-9 2-MethyltetrahydrofuranDermalLD504500 mg/kg (rabbit)Inhalative LC50/4H 6000 ppm/4H (rat)Skin irritation or corrosion:Causes severe skin burns.Eye irritation or corrosion:Causes serious eye damage.Sensitization:No sensitizing effects known.Germ cell mutagenicity:No effects known.Carcinogenicity:No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.Reproductive toxicity:No effects known.Specific target organ system toxicity – repeated exposure:No effects known.Specific target organ system toxicity – single exposure:No effects known.Aspiration hazard:No effects known.Subacute to chronic toxicity:No effects known.Additional toxicological information:To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.The product shows the following dangers according to internally approved calculation methods for preparations:Corrosive

SECTION 12. ECOLOGICAL INFORMATION

ToxicityAquatic toxicity:No further relevant information available.Persistence and degradabilityNo further relevant information available.Bioaccumulative potentialNo further relevant information available.Mobility in soilNo further relevant information available.Additional ecological information:General notes:Do not allow material to be released to the environment without proper governmental permits.Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.Avoid transfer into the environment.Results of PBT and vPvB assessmentPBT:Not applicable.vPvB:Not applicable.Other adverse effectsNo further relevant information available.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methodsRecommendationConsult state, local or national regulations to ensure proper disposal.Uncleaned packagings:Recommendation:Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-NumberDOT, IMDG, IATAUN2924UN proper shipping nameDOTFlammable liquids, corrosive, n.o.s.IMDG, IATAFLAMMABLE LIQUID, CORROSIVE, N.O.S.Transport hazard class(es)DOTClass3 Flammable liquids.Label3+8Class3 (FC) Flammable liquidsLabel3+8IMDG, IATAClass3 Flammable liquids.Label3+8Packing groupDOT, IMDG, IATAIIEnvironmental hazards:Marine pollutant (IMDG):NoSpecial precautions for userWarning: Flammable liquidsTransport in bulk according to Annex II of MARPOL73/78 and the IBC CodeNot applicable.Transport/Additional information:DOTMarine Pollutant (DOT):NoUN “Model Regulation”:UN2924, Flammable liquids, corrosive, n.o.s., 3 (8), II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixtureGHS label elementsThe product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)Hazard pictogramsGHS02GHS05Signal wordDangerHazard-determining components of labeling:Phenylmagnesium bromideHazard statementsH225 Highly flammable liquid and vapor.H314 Causes severe skin burns and eye damage.Precautionary statementsP210Keep away from heat/sparks/open flames/hot surfaces. No smoking.P260Do not breathe dust/fume/gas/mist/vapours/spray.P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P405Store locked up.P501Dispose of contents/container in accordance with local/regional/national/international regulations.National regulationsAll components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.Some or all of the components of this product are not listed on the Canadian Domestic Substances List (DSL) or the Canadian Non-Domestic Substances List(NDSL).SARA Section 313 (specific toxic chemical listings)None of the ingredients are listed.California Proposition 65Prop 65 – Chemicals known to cause cancerNone of the ingredients are listed.Prop 65 – Developmental toxicityNone of the ingredients are listed.Prop 65 – Developmental toxicity, femaleNone of the ingredients are listed.Prop 65 – Developmental toxicity, maleNone of the ingredients are listed.Information about limitation of use:For use only by technically qualified individuals.Other regulations, limitations and prohibitive regulationsSubstance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.None of the ingredients are listed.The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.None of the ingredients is listed.Annex XIV of the REACH Regulations (requiring Authorisation for use)None of the ingredients is listed.Chemical safety assessment:A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

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